Functionalized 3D Architected Materials via Thiol-Michael Addition and Two-Photon Lithography

Functionalized 3D Architected Materials via Thiol-Michael Addition and Two-Photon Lithography.

Fabrication of functionalized 3D architected materials is achieved by a facile method using functionalized acrylates synthesized via thiol-Michael addition, which are then polymerized using two-photon lithography. A wide variety of functional groups can be attached, from Boc-protected amines to fluoroalkanes. Modification of surface wetting properties and conjugation with fluorescent tags are d...

Fabrication of 3d Micro-architected/ Nano-architected Materials

Spatial and Temporal Control of Thiol-Michael Addition via Photocaged Superbase in Photopatterning and Two-Stage Polymer Networks Formation

Photochemical processes enable spatial and temporal control of reactions, which can be implemented as an accurate external control approach in both polymer synthesis and materials applications. "Click" reactions have also been employed as efficient tools in the same field. Herein, we combined photochemical processes and thiol-Michael "click" reactions to achieve a "photo-click" reaction that ca...

3D manufacturing of micro and nano- architected materials

Reducing mass without sacrificing mechanical integrity and performance is a critical goal in a vast range of applications. Introducing a controlled amount of porosity in a strong and dense material (hence fabricating a cellular solid) is an obvious avenue to weight reduction. The mechanical effectiveness of this strategy, though, depends strongly on the architecture of the resulting cellular ma...

Two-photon diffraction and quantum lithography.

We report a proof-of-principle experimental demonstration of quantum lithography. Utilizing the entangled nature of a two-photon state, the experimental results have beaten the classical diffraction limit by a factor of 2. This is a quantum mechanical two-photon phenomenon but not a violation of the uncertainty principle.